9. COORDINATION COMPOUNDS

1. Choose the most correct option.

i. The oxidation state of cobalt ion in the complex [Co(NH3)5Br]SO4 is

a. +2

b. +3
c. +1

d. +4

Answer:- +3

Explanation:

It is known that the sulfate ion carries a charge of -2, represented as \[\ce{SO^{2-}_4}\]

Now, consider the complex ion [Co(NH3)5Br]2+

The oxidation state of NH3 is 0

The oxidation state of Br is -1

Let the oxidation state of the Cobalt ion be represented as x

So, x + (3 × 0) × 5 + (-1) = +2

⇒ x – 1 = +2

⇒ x = +3

Therefore, the oxidation state of the cobalt ion is +3.

9. COORDINATION COMPOUNDS page No. 207