10 Halogen Derivaties
2. Do as directed.
ii. Write structure and IUPAC name of the major product in each of the following reaction.
\[\begin{array}{cc}
\ce{CH3 – CH – CH2Cl + NaI ->[Acetone] CH3 – CH – CH2 – I + NaCl↓}\\
\phantom{….}|\phantom{…………………………..}\phantom{..}|\phantom{………………}\\
\ce{\phantom{….}\underset{\text{1-Chloro-2-methylpropane}}{CH3}}\phantom{…………..}
\ce{\phantom{….}\underset{\text{1-Iodo-2-methylpropane}}{CH3}}\phantom{…………….}
\end{array}\]
\[\ce{\underset{\text{Bromoethane}}{3CH3CH2Br} + SbF3 -> \underset{\text{Fluoroethane}}{3CH3CH2F} + SbBr3↓}\]
\[\begin{array}{cc}
\ce{CH3 – CH – CH = CH2 + HBr ->[peroxide] CH3 – CH – CH2 – CH2}\\
\phantom{…….}|\phantom{…………………………………}|\phantom{……………}|\phantom{}\\
\ce{\phantom{……..}CH3}\ce{\phantom{………………….}\underset{\text{1-Bromo-3-methylbutane
(Major product)}}{CH3}}\ce{Br}
\end{array}\]
