ix. pH of a weak monobasic acid is 3.2 in its 0.02 M solution. Calculate its dissociation constant
3. Answer the following in brief :
ix. pH of a weak monobasic acid is 3.2 in its 0.02 M solution. Calculate its dissociation constant
Answer:-
\begin{align*}
\text{Given:} \\
\text{pH} &= 3.2 \\
\text{Concentration Dissociation} &= 0.02 \, \text{M} \\
\text{Dissociation constant (} K_a \text{)} &= ? \\
\text{Calculation:} \\
K_a &= \frac{\left(\alpha^2\right)}{(1 - \alpha)} \\
\alpha &= \frac{[H^+]}{C} \\
\text{pH} &= -\log_{10}[H^+] \\
3.2 &= -\log_{10}[H^+] \\
-3.2 &= \log_{10}[H^+] \\
10^{-3.2} &= [H^+] \\
6.3 \times 10^{-4} &= [H^+] \\
\alpha &= \frac{[H^+]}{C} \\
&= \frac{6.3 \times 10^{-4}}{0.02} \\
&= 0.0315 \\
K_a &= \frac{\left(0.02 \times 0.0315\right)^2}{1 - 0.0315} \\
&= \frac{0.02 \times 0.000992}{0.9685} \\
&= \frac{0.02 \times 9.92 \times 10^{-4}}{1} \\
&= 0.1984 \times 10^{-4}
\end{align*}