Solid State Class 12 Chemistry Maharashtra Board Textbook Solution

13. Explain with diagram, Frenkel defect. What are the conditions for its formation? What is its effect on density and electrical neutrality of the crystal?

Answer:-

If cation loses its original lattices site and occupies an interstitial  void, this defect results. It creates a vacancy defect at its original lattice site and an interstitial defect at its new location.
It is found in crystals:
(i) with low co.no.
(ii) Where there is large difference in the size of cation and anions e.g. ZnS, AgCl, AgBr, AgI.
Due to this defect, the density doesn’t change. Due to the presence of holes, crystals conduct electricity stability decreases. Dielectric constant increases  similar charges come closer.
frenkel defect

Solid State Class 12 Chemistry Maharashtra Board Textbook Solution