12. ALDEHYDES, KETONES AND CARBOXYLIC ACIDS
3. Answer in brief.
iv. Write reaction showing conversion of Acetaldehyde into acetaldehyde dimethyl acetal.
Answer:-
Step 1:
\[\begin{array}{cc}
\ce{H3C\phantom{…………………………}}\ce{H\phantom{………}}\\
|\phantom{…………………………….}|\phantom{………}\\
\phantom{.}\ce{C = O + CH3 – OH ⇌[dry HCl][dil.HCl] H3C – C – OCH3}\\
\phantom{.}|\phantom{…………………………….}|\phantom{………}\\
\phantom{..}\ce{\underset{Acetaldehyde}{H}}\phantom{………………….}\ce{\underset{Hemiacetal (unstable)}{OH}}\phantom{……..}
\end{array}\]
Step 2:
\[\begin{array}{cc}
\ce{H\phantom{……………………………….}}\ce{H\phantom{………}}\\
|\phantom{………………………………..}|\phantom{………}\\
\ce{H3C – C – OCH3 + CH3 – OH ⇌[dry HCl][dil.HCl] H3C – C – OCH3 + H2O}\\
|\phantom{………………………………..}|\phantom{………}\\
\ce{\underset{Hemiacetal (unstable)}{H}\phantom{………………..}}
\ce{\underset{Acetaldehyde dimethyl acetal (stable)}{OCH3}\phantom{.}}
\end{array}\]
The conversion of acetaldehyde into acetaldehyde dimethyl acetal involves the reaction of acetaldehyde with methanol in the presence of an acid catalyst. Here’s the reaction:
Conversion of Acetaldehyde to Acetaldehyde Dimethyl Acetal:
In this reaction:
Acetaldehyde (CH3CHO) reacts with two molecules of methanol (CH3OH).
An acid catalyst (often sulfuric acid, H2SO4) is typically used to facilitate the reaction.
The product formed is acetaldehyde dimethyl acetal (CH3CH(OMe)2).
Water (H2O) is also produced as a byproduct of the reaction.
Acetaldehyde dimethyl acetal is a common acetal compound formed by the reaction of aldehydes or ketones with methanol in the presence of acid. It is used as a protecting group in organic synthesis and as a solvent.
12. ALDEHYDES, KETONES AND CARBOXYLIC ACIDS page 281
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