Chapter 2 Solutions Class 12 Chemistry Maharashtra Board Textbook Solution
3. Answer the following.
viii. Using Raoult’s law, how will you show that ΔP = 0 1 P x2 ? Where x2 is the mole fraction of solute in the solution and 0 1 P vapour pressure of pure solvent.
According to Rault’s law.
P1 = x1 P10
where,
P1 = Partial pressure of solvent
P10 = vapour pressure of pure solvent
x1 = mole fraction of solvent.
We can also write the above equation like that —
P10 – P1 = P10 – x1P10
⇒ ΔP1 = P10 (1 – x1) [ΔP1 = P10 – P1]
ΔP1 = reduction in the vapour pressure of solvent (ΔP1).
⇒ ΔP1 = P10x2 [x2 = (1 – x1)]
x2 = mole fraction of solute.
Hence, ΔP1 = P10x2
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