Chapter 2 Solutions Class 12 Chemistry Maharashtra Board Textbook Solution
6. Obtain the relationship between freezing point depression of a solution containing
nonvolatile nonelctrolyte and its molar mass.
1. The freezing point depression (∆Tf) is directly proportional to the molality of the solution.
Thus, ∆Tf = Kf · m2. Suppose we prepare a solution by dissolving W2 g of solute in W1 g of solvent.
Moles of solute in W1 g of solvent = √W2/M2,
where M2 is the molar mass of the solute.
Mass of solvent = W1 g = W1/1000 kg
3. The molality is expressed as,
m = Moles of solute / Mass of solvent in kg,
m = (1000W2 / (M2 mol)) / (W1/1000 kg)
4. Substituting equation (2) in equation (1), we get,
∆Tf = (1000KfW2) / (M2W1)
Hence,
M2 = (1000KfW2) / (∆TfW1)
Chapter 2 Solutions Class 12 Chemistry Maharashtra Board Textbook Solution
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