11. ALCOHOLS, PHENOLS AND ETHERS

3. Answer in brief.

vi. Give a simple chemical test to distinguish between ethanol and ethyl bromide.

Answer:-

i. Ethanol on reaction with a very strong base like alkali metal Na or K gives sodium or potassium ethoxide with the liberation of hydrogen gas.

\[\ce{2CH3CH2 – OH + 2Na -> 2CH3CH2O^-Na+ + H2_{(g)}↑}\]

ii. Ethyl bromide on reaction with sodium metal does not liberate hydrogen gas.

\[\ce{2CH3CH2Br + 2Na -> CH3CH2 – CH2CH3 + 2NaBr}\]

v. Give the equations of the reactions for the preparation of phenol from isopropyl benzene

11. ALCOHOLS, PHENOLS AND ETHERS 253