Chapter 2  Solutions Class 12 Chemistry Maharashtra Board Textbook Solution

3. Answer the following.

vii. Why vapour pressure of a solvent is lowered by dissolving a nonvolatile solute into it?

Answer:-

Vapour pressure of a liquid depends on the ease with which the molecules escape from the surface of liquid. When nonvolatile solute is dissolved in a solvent, some of the surface molecules of solvent are replaced by nonvolatile solute molecules. These solute molecules do not contribute to vapour above the solution. Thus, the number of solvent molecules available for vaporization per unit surface area of solution is less than the number at  the surface of pure solvent. As a result the solvent molecules at the surface of solution vaporize at a slower rate than pure solvent. This results in lowering of vapour pressure .

Chapter 2  Solutions Class 12 Chemistry Maharashtra Board Textbook Solution